Guided Ideographic Spin System Model Optimization

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Mixture Simulation

Mol to jpg conversion

Simulation: simulation_1

BMRB entry

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Download simulation data

View entry XML

Download entry NMR-STAR

Download entry NMReDATA

External links:

NMRFAM Servers

pKa (R. Williams)

1H NMR (Hans J. Reich)

2-[2,3-Di(hexanoyloxy)propoxy-hydroxyphosphoryl]oxyethyl-trimethylazanium

Simulation outputs:

InChI=1S/C20H40NO8P/c1-6-8-10-12-19(22)26-16-18(29-20(23)13-11-9-7-2)17-28-30(24,25)27-15-14-21(3,4)5/h18H,6-17H2,1-5H3/p+1/t18-/m0/s1 Parameter Value
Field strength 499.84(MHz)
RMSD of the fit 0.01563
Temperature 298 K
pH 7.4
InChI InChI=1S/C20H40NO8P/c1-6-8-10-12-19(22)26-16-18(29-20(23)13-11-9-7-2)17-28-30(24,25)27-15-14-21(3,4)5/h18H,6-17H2,1-5H3/p+1/t18-/m0/s1
Note 1 Processed by Tevin Li

Sample description:

Compound Type Concentration
2-[2,3-di(hexanoyloxy)propoxy-hydroxyphosphoryl]oxyethyl-trimethylazanium solute 100mM
Chloroform-d solvent 100.0%
TMS reference 0.05%
Show/Hide Spin System Matrix

Spin System Matrix

31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
31 0.893 0 0 0 0 0 0 0 0 0 0 0 0 0 0 6.626 6.626 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
32 0 0.893 -12.4 0 0 0 0 0 0 0 0 0 0 0 0 6.626 6.626 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
33 0 0 0.893 0 0 0 0 0 0 0 0 0 0 0 0 6.626 6.626 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
34 0 0 0 0.893 0 0 0 0 0 0 0 0 0 0 0 0 0 6.771 6.771 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
35 0 0 0 0 0.893 -12.4 0 0 0 0 0 0 0 0 0 0 0 6.771 6.771 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
36 0 0 0 0 0 0.893 0 0 0 0 0 0 0 0 0 0 0 6.771 6.771 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
37 0 0 0 0 0 0 3.344 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
38 0 0 0 0 0 0 0 3.344 -12.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
39 0 0 0 0 0 0 0 0 3.344 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
40 0 0 0 0 0 0 0 0 0 3.344 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
41 0 0 0 0 0 0 0 0 0 0 3.344 -12.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
42 0 0 0 0 0 0 0 0 0 0 0 3.344 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
43 0 0 0 0 0 0 0 0 0 0 0 0 3.344 -12.4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
44 0 0 0 0 0 0 0 0 0 0 0 0 0 3.344 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
45 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.344 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
46 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.288 -12.532 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
47 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.31 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
48 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.294 -11.856 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
49 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.304 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
50 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.281 -11.596 0 0 3.388 8.631 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
51 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.313 0 0 4.456 3.363 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
52 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.288 -15.826 0 0 1.965 8.882 0 0 0 0 0 0 0 0 0 0 0 0 0
53 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.31 0 0 8.776 1.964 0 0 0 0 0 0 0 0 0 0 0 0 0
54 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.582 -10.136 0 0 8.614 6.345 0 0 0 0 0 0 0 0 0 0 0
55 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.602 0 0 7.362 8.605 0 0 0 0 0 0 0 0 0 0 0
56 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.601 -14.573 0 0 -0.031 10.089 0 0 0 0 0 0 0 0 0
57 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1.579 0 0 10.376 -0.031 0 0 0 0 0 0 0 0 0
58 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2.271 -17.259 0 0 0 0 0 0 0 0 0 0 0
59 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2.313 0 0 0 0 0 0 0 0 0 0 0
60 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2.297 -13.581 0 0 0 0 0 0 0 0 0
61 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2.287 0 0 0 0 0 0 0 0 0
62 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.288 -12.983 7.438 10.632 0 0 0 0 0
63 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.276 3.553 7.438 0 0 0 0 0
64 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.281 -12.627 0 0 0 0 0
65 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.285 0 0 0 0 0
66 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.767 1.642 0 0 1.441
67 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3.767 0 0 9.072
68 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.389 -12.162 3.81
69 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4.126 7.354
70 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5.191

Spectra

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PPM Amplitude Peak Type
0.119316 standard
0.247023 standard
0.132136 standard
0.00291325 standard
0.0079556 standard
0.010209 standard
0.01151 standard
0.0182793 standard
0.039188 standard
0.0634421 standard
0.105935 standard
0.134968 standard
0.160481 standard
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0.113769 standard
0.057414 standard
0.0199022 standard
0.018563 standard
0.0089025 standard
0.00541128 standard
0.00277337 standard
0.000779125 standard
0.00115413 standard
0.001443 standard
0.00283704 standard
0.00510604 standard
0.00785012 standard
0.0304414 standard
0.0390511 standard
0.0562632 standard
0.0688283 standard
0.0926331 standard
0.0866586 standard
0.0755772 standard
0.0609646 standard
0.0301261 standard
0.0148711 standard
0.0178877 standard
0.00641916 standard
0.00478813 standard
0.00141425 standard
0.00112425 standard
0.0100314 standard
0.015713 standard
0.0468693 standard
0.154354 standard
0.111239 standard
0.111621 standard
0.138955 standard
0.04387 standard
0.0132326 standard
0.013408 standard
0.00930397 standard
1.0 standard
0.0568351 standard
0.0742041 standard
0.0564381 standard
0.0222274 standard
0.0246645 standard
0.0283815 standard
0.0265179 standard
0.132599 standard
0.0299516 standard
0.0303443 standard
0.0256599 standard
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0.0129769 standard
0.016933 standard
0.0249877 standard
0.016932 standard
0.0129754 standard
0.00661512 standard
0.0312111 standard
0.0902391 standard
0.075564 standard
0.353036 standard
0.312343 standard
0.194846 standard
0.239743 standard
0.300387 standard
0.204359 standard
0.133564 standard
0.0920453 standard
0.063825 standard
0.147971 standard
0.145504 standard
0.13891 standard
0.120241 standard
0.0344091 standard
0.00723912 standard
1.0 standard
0.0637321 standard
0.0943221 standard
0.225451 standard
0.0226711 standard
0.0239621 standard
0.0264921 standard
0.0105121 standard
0.0464642 standard
0.093236 standard
0.08453 standard
0.0819773 standard
0.324778 standard
0.245347 standard
0.219152 standard
0.212513 standard
0.249817 standard
0.122989 standard
0.116552 standard
0.0868391 standard
0.0709641 standard
0.0712971 standard
0.03692 standard
0.0157051 standard
0.00871712 standard
0.00770513 standard
0.0137721 standard
0.119556 standard
0.122296 standard
0.16078 standard
0.099805 standard
0.00319912 standard
1.0 standard
0.0570641 standard
0.0816881 standard
0.0694121 standard
0.0243031 standard
0.0623211 standard
0.196143 standard
0.0285811 standard
0.0208251 standard
0.0176101 standard
0.0205671 standard
0.0254891 standard
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0.322165 standard
0.227649 standard
0.223102 standard
0.217605 standard
0.22363 standard
0.0894891 standard
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0.112046 standard
0.0906372 standard
0.0731242 standard
0.06749 standard
0.0321871 standard
0.00362313 standard
0.00507313 standard
0.005958 standard
0.00624813 standard
0.00437913 standard
0.00463713 standard
0.12448 standard
0.136877 standard
0.169489 standard
0.103221 standard
0.051622 standard
0.00206013 standard
0.00208813 standard
1.0 standard
0.0557431 standard
0.0783211 standard
0.064458 standard
0.0189401 standard
0.0260331 standard
0.0507191 standard
0.163915 standard
0.026925 standard
0.0216371 standard
0.0158871 standard
0.0191571 standard
0.0250531 standard
0.0162781 standard
0.0110791 standard
0.115493 standard
0.326597 standard
0.223861 standard
0.0101851 standard
0.223699 standard
0.220044 standard
0.213809 standard
0.0620613 standard
0.064682 standard
0.058743 standard
0.0907545 standard
0.107253 standard
0.076526 standard
0.0748151 standard
0.065352 standard
0.00337013 standard
0.00399013 standard
0.00382913 standard
0.00484912 standard
0.00345913 standard
0.00429613 standard
0.128429 standard
0.132232 standard
0.17197 standard
0.0958845 standard
0.0681861 standard
0.00356812 standard
0.00195012 standard
0.00187712 standard
1.0 standard
0.0554351 standard
0.0775041 standard
0.0630861 standard
0.0185961 standard
0.0253791 standard
0.0469113 standard
0.0882371 standard
0.1545 standard
0.0264291 standard
0.0220221 standard
0.0153981 standard
0.0186871 standard
0.0250111 standard
0.0162251 standard
0.0112121 standard
0.122187 standard
0.332636 standard
0.221407 standard
0.00786313 standard
0.00879013 standard
0.223522 standard
0.224592 standard
0.216124 standard
0.0583401 standard
0.0489303 standard
0.0558401 standard
0.095605 standard
0.107757 standard
0.0804291 standard
0.0758353 standard
0.0637948 standard
0.00375212 standard
0.00275713 standard
0.00236913 standard
0.00213712 standard
0.00267113 standard
0.00351412 standard
0.00313912 standard
0.00430312 standard
0.128581 standard
0.127789 standard
0.173114 standard
0.0938439 standard
0.069225 standard
0.00363212 standard
0.00200312 standard
0.00171212 standard
1.0 standard
0.055268 standard
0.0768331 standard
0.0621461 standard
0.0185321 standard
0.0249121 standard
0.043929 standard
0.0725521 standard
0.149847 standard
0.0727792 standard
0.0260471 standard
0.0223123 standard
0.0150421 standard
0.0184161 standard
0.0249411 standard
0.0161831 standard
0.0113161 standard
0.168354 standard
0.390353 standard
0.220904 standard
0.00624225 standard
0.00738125 standard
0.147542 standard
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0.21104 standard
0.058877 standard
0.008608 standard
0.00418712 standard
0.00407313 standard
0.00372612 standard
0.00333212 standard
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0.0347434 standard
0.045298 standard
0.053169 standard
0.0987382 standard
0.124481 standard
0.0821261 standard
0.0730261 standard
0.0466228 standard
0.0187543 standard
0.0036 standard
0.002979 standard
0.00141812 standard
0.00108212 standard
0.001895 standard
0.0041835 standard
0.0067675 standard
0.0698965 standard
0.0941656 standard
0.129854 standard
0.142767 standard
0.146957 standard
0.114866 standard
0.0559153 standard
0.00688102 standard
0.00302104 standard
0.00143612 standard
1.0 standard
0.055233 standard
0.07481 standard
0.0583024 standard
0.0197702 standard
0.0238911 standard
0.0324599 standard
0.034768 standard
0.141047 standard
0.0429774 standard
0.0406103 standard
0.0250272 standard
0.0236926 standard
0.013743 standard
0.0174601 standard
0.024769 standard
0.0161952 standard
0.0118601 standard
0.153763 standard
0.335406 standard
0.182656 standard
0.00236813 standard
0.006362 standard
0.00815325 standard
0.009767 standard
0.016356 standard
0.0776887 standard
0.18442 standard
0.190976 standard
0.175396 standard
0.0590282 standard
0.00465825 standard
0.00392013 standard
0.00128012 standard
0.00130313 standard
0.00130313 standard
0.00145413 standard
0.00159713 standard
0.00249612 standard
0.00375925 standard
0.0574513 standard
0.0978368 standard
0.122524 standard
0.0933262 standard
0.0749928 standard
0.0436222 standard
0.0173405 standard
0.00447804 standard
0.00362904 standard
0.00137012 standard
0.00113313 standard
0.00631514 standard
0.010677 standard
0.0549647 standard
0.144251 standard
0.129177 standard
0.126688 standard
0.12869 standard
0.0495509 standard
0.0105847 standard
0.0052098 standard
1.0 standard
0.05596 standard
0.0748165 standard
0.0575459 standard
0.020895 standard
0.0243463 standard
0.0298972 standard
0.0296841 standard
0.139058 standard
0.0342861 standard
0.0339474 standard
0.0252414 standard
0.0241431 standard
0.013447 standard
0.017319 standard
0.02482 standard
0.016529 standard
0.0125274 standard
0.131169 standard
0.277295 standard
0.149253 standard
0.00260113 standard
0.0070525 standard
0.00915641 standard
0.0107821 standard
0.0162856 standard
0.0449953 standard
0.118752 standard
0.166056 standard
0.153574 standard
0.152345 standard
0.13493 standard
0.0567456 standard
0.018182 standard
0.0147825 standard
0.005085 standard
0.00466562 standard
0.00264004 standard
0.000948 standard
0.001296 standard
0.001467 standard
0.00260813 standard
0.004185 standard
0.00677525 standard
0.0398272 standard
0.0584321 standard
0.0885412 standard
0.0983475 standard
0.0808772 standard
0.0846234 standard
0.061228 standard
0.0587449 standard
0.0406373 standard
0.0172896 standard
0.00561968 standard
0.00422502 standard
0.00142213 standard
0.00112712 standard
0.00830727 standard
0.0137511 standard
0.0495088 standard
0.163632 standard
0.155103 standard
0.0458442 standard
0.0124623 standard
0.00737087 standard
1.0 standard
0.0567328 standard
0.0742192 standard
0.056684 standard
0.0218805 standard
0.024403 standard
0.0291499 standard
0.0274595 standard
0.135667 standard
0.0313355 standard
0.0315468 standard
0.025466 standard
0.024616 standard
0.0129761 standard
0.016914 standard
0.025035 standard
0.016908 standard
0.0130041 standard
0.119293 standard
0.246979 standard
0.132108 standard
0.00291225 standard
0.00795468 standard
0.010203 standard
0.0114997 standard
0.0182982 standard
0.0390914 standard
0.0635099 standard
0.105901 standard
0.13483 standard
0.160519 standard
0.145913 standard
0.113743 standard
0.0574495 standard
0.0198696 standard
0.0185861 standard
0.00889757 standard
0.00541017 standard
0.0027735 standard
0.000779 standard
0.00115313 standard
0.00144512 standard
0.00283712 standard
0.00510616 standard
0.00787353 standard
0.0304334 standard
0.0390383 standard
0.0562512 standard
0.0688063 standard
0.0926088 standard
0.0866426 standard
0.0757051 standard
0.0608163 standard
0.0301079 standard
0.0148676 standard
0.0179029 standard
0.00641425 standard
0.00478811 standard
0.00141313 standard
0.00112625 standard
0.0100304 standard
0.0157119 standard
0.0468634 standard
0.154321 standard
0.111215 standard
0.111595 standard
0.138922 standard
0.0438641 standard
0.0132315 standard
0.0134081 standard
0.00930686 standard
1.0 standard
0.0568221 standard
0.0741881 standard
0.0564249 standard
0.022227 standard
0.0246625 standard
0.0283786 standard
0.0265159 standard
0.132653 standard
0.0299476 standard
0.0303393 standard
0.0256579 standard
0.0249087 standard
0.0129744 standard
0.016929 standard
0.0249836 standard
0.0169063 standard
0.0129684 standard
0.113681 standard
0.231638 standard
0.123456 standard
0.00763635 standard
0.010316 standard
0.0125786 standard
0.0205361 standard
0.0326252 standard
0.0508951 standard
0.052734 standard
0.090857 standard
0.103315 standard
0.103189 standard
0.127167 standard
0.134367 standard
0.117971 standard
0.113388 standard
0.101484 standard
0.0215935 standard
0.0215373 standard
0.0216594 standard
0.00965304 standard
0.00595541 standard
0.00301545 standard
0.00111738 standard
0.00133604 standard
0.00309102 standard
0.00579396 standard
0.00905102 standard
0.0114244 standard
0.0299345 standard
0.0518618 standard
0.0634369 standard
0.0977716 standard
0.0889888 standard
0.0731358 standard
0.0491085 standard
0.055307 standard
0.0268877 standard
0.0186664 standard
0.0116244 standard
0.00699137 standard
0.00533506 standard
0.00136 standard
0.00110425 standard
0.0112512 standard
0.0172979 standard
0.00596704 standard
0.044696 standard
0.109484 standard
0.0722513 standard
0.0778636 standard
0.081317 standard
0.110571 standard
0.042959 standard
0.0187042 standard
0.00628887 standard
0.0142011 standard
0.0145425 standard
0.0108214 standard
1.0 standard
0.0567599 standard
0.0745568 standard
0.05605 standard
0.0224372 standard
0.0248711 standard
0.0279426 standard
0.0259469 standard
0.12888 standard
0.0291626 standard
0.0296267 standard
0.0257882 standard
0.0250921 standard
0.012951 standard
0.0168586 standard
0.0249569 standard
0.0168802 standard
0.0129711 standard
0.111517 standard
0.224665 standard
0.118948 standard
0.00735478 standard
0.0109214 standard
0.0132026 standard
0.0215236 standard
0.0299041 standard
0.048684 standard
0.0496231 standard
0.0809512 standard
0.0937296 standard
0.114167 standard
0.133528 standard
0.106052 standard
0.0980426 standard
0.0456057 standard
0.0276588 standard
0.0236079 standard
0.0113151 standard
0.00634972 standard
0.00330328 standard
0.001078 standard
0.00129304 standard
0.00340035 standard
0.00609541 standard
0.0101531 standard
0.0122924 standard
0.0306385 standard
0.0588274 standard
0.0555766 standard
0.0790378 standard
0.0788726 standard
0.0644453 standard
0.084245 standard
0.0639225 standard
0.0446606 standard
0.0235159 standard
0.019031 standard
0.00761602 standard
0.00576388 standard
0.0013215 standard
0.00106512 standard
0.0124361 standard
0.018704 standard
0.0417665 standard
0.0684124 standard
0.0694736 standard
0.0828924 standard
0.079227 standard
0.0840415 standard
0.0833836 standard
0.0698453 standard
0.0626826 standard
0.0534173 standard
0.0413725 standard
0.0194737 standard
0.0151993 standard
0.0155315 standard
0.0121292 standard
1.0 standard
0.0573202 standard
0.0740961 standard
0.0559709 standard
0.0226065 standard
0.0249096 standard
0.0275384 standard
0.025569 standard
0.124874 standard
0.0286191 standard
0.0291207 standard
0.0258656 standard
0.0252 standard
0.0129143 standard
0.016895 standard
0.0249712 standard
0.0167978 standard
0.0128776 standard
0.110262 standard
0.221815 standard
0.117161 standard
0.00745172 standard
0.0114184 standard
0.013062 standard
0.0217859 standard
0.0301334 standard
0.0482552 standard
0.0494208 standard
0.060419 standard
0.080325 standard
0.0834538 standard
0.0844502 standard
0.103956 standard
0.121231 standard
0.0989618 standard
0.0971728 standard
0.0449445 standard
0.0448707 standard
0.0282824 standard
0.0250591 standard
0.012184 standard
0.00655569 standard
0.00342001 standard
0.00106404 standard
0.00127313 standard
0.0036082 standard
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